Synthesis of propargylic fluorides from allenylsilanes

文献信息

发布日期 2006-08-23

DOI 10.1039/B610013A

影响因子 6.222

作者

Laurence Carroll, Mª Carmen Pacheco, Ludivine Garcia, Véronique Gouverneur

查看原文

摘要

Allenylsilanes reacted at room temperature in acetonitrile with Selectfluor, an electrophilic fluorinating reagent, to give secondary propargylic fluorides in moderate to good yields; mechanistically, a side-product resulting from a 1,2-silyl shift testifies to the presence of a cationic intermediate.

期刊推荐

Journal of the Royal Society of New Zealand

Cellular Polymers

Chemistry Letters

Ceramics International

Fire Safety Journal

Chemical Society Reviews

Geotextiles and Geomembranes

Composites Science and Technology

Composite Structures

Heterocycles

来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Synthesis of propargylic fluorides from allenylsilanes

文献信息

期刊推荐

相关文献

Functionalisation of MWCNTs with poly(lauryl acrylate) polymerised by Cu(0)-mediated and RAFT methods

Poly(acrylate) with a tetraphenylethene pendant with aggregation-induced emission (AIE) characteristics: highly stable AIE-active polymer nanoparticles for effective detection of nitro compounds

Heterogeneous organocatalysts composed of microporous polymer networks assembled by Tröger's base formation

Catch and release: photocleavable cationic diblock copolymers as a potential platform for nucleic acid delivery

CO2-Responsive graft copolymers: synthesis and characterization

Tumor-targeted aggregation of pH-sensitive nanocarriers for enhanced retention and rapid intracellular drug release

Palladium nanoparticles supported on a carbazole functionalized mesoporous organic polymer: synthesis and their application as efficient catalysts for the Suzuki–Miyaura cross coupling reaction

The living anionic polymerization of activated aziridines: a systematic study of reaction conditions and kinetics

Non-conventional fluorescent biogenic and synthetic polymers without aromatic rings

Reduction- and thermo-sensitive core-cross-linked polypeptide hybrid micelles for triggered and intracellular drug release

您可能还喜欢

如何储存1,2-环己二酮环乙缩醛(CAS号：4746-96-7)？

Ecopladib(CAS号：381683-92-7)的市场或研究趋势如何？

2,3-Dimethyl-3H-imidazo[4,5-c]pyridine(CAS号：52538-09-7)通常如何合成？

2,3,4,5-tetrahydro-1H-3-苯并氮杂环;盐酸盐(CAS号：17379-01-0)的市场或研究趋势如何？

解草嗪(CAS号：68-90-6)安全吗？

如何储存盐酸甘氨酸丁酯(CAS号：13048-99-2)？

什么是2-Iodo-N,N-dimethylbenzamide(CAS号：54616-46-5)？

如何储存2-氨基-N-环己基乙酰胺(CAS号：16817-90-6)？

5-溴-2-(4H-1,2,4-三唑-4-基)吡啶(CAS号：959240-99-4)的市场或研究趋势如何？

2,4-二溴-6-三氟甲基嘧啶(CAS号：785778-00-9)通常如何合成？

来源期刊

Chemical Communications

推荐化合物

4-Methyl-3-morpholinecarboxylic acid hydrochloride (1:1)

2,2-dideuterio-2-(3,4,5,6-tetradeuterio-2-pyridyl)acetic acid;hydrochloride

(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid

N-[2-(4-Hydroxyphenoxy)-4-nitrophenyl]methanesulfonamide

6-CHLORO-2,3-DIOXO-1,2,3,4-TETRAHYDROQUINOXALINE, 97

推荐供应商