A long-term stable zinc metal anode enabled by a mannitol additive

文献信息

发布日期 2023-10-20
DOI 10.1039/D3TA04700H
影响因子 12.732
作者

Dongdong Zhang, Jin Cao, Zhiqiang Dai, Rungroj Chanajaree, Chengwu Yang, Xiang Wu, Xinyu Zhang


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摘要

Despite the promising potential of zinc-ion batteries (ZIBs) for large-scale energy storage applications, their electrochemical performance is still hindered by zinc dendrites and side reactions. To address these challenges, the optimization of electrolyte composition emerges as a practical and straightforward approach to enhance the coulombic efficiency (CE) and Zn plating/stripping reversibility of ZIBs. Here, mannitol stands out due to its abundance of polar groups and cost-effectiveness, and an electrolyte mixture consisting of 0.02 M mannitol and 2 M ZnSO4 is demonstrated, resulting in an impressive improvement in Zn reversibility compared to the pure ZnSO4 electrolyte. Density functional theory (DFT) calculations and spectroscopic analysis shed light on mannitol's capability to reconstruct the solvation structure of Zn2+ and replace free water molecules. The inhibited dendrite growth on the zinc metal anode is further confirmed through in situ characterization. This work paves the way for the development of long-lifespan ZIBs.

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Contents list

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来源期刊

Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
自引率: 4.7%
年发文量: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

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